Colloidal Dispersion Rheology
(a
two-day course) |
|
October 23 and 24, 2010 (Saturday and Sunday) |
Microrheology: Theory, Practice and
Applications (a one-day course) |
|
October 24, 2010 (Sunday) |
Option is available for participants to attend the first day of
Colloidal Dispersion Rheology course on Saturday and the
Microrheology: Theory, Practice and Applications course on
Sunday. |
All classes will begin
at 8:30 am in the
Eldorado Hotel & Spa, which is adjacent to the
Hilton
of Santa Fe. |
The short courses are held in conjunction with the
82nd Annual Meeting of The
Society of Rheology (October 24 - 28, 2010)
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Instructor Biosketches
With over 50 years of academic and industrial research experience
in the colloid rheology laboratory, including over 100 publications
and patents on the topic, Professors
Mewis and
Wagner
have prepared a short course designed for introducing a beginning
colloid rheologist to the field. This course is based on a text
currently being published. Both have lectured extensively on the
topic and have taught short courses at both the beginner and more
advanced levels, including courses for the Society of Rheology in
the US and the European Rheology Society in Europe.
Professor
Eric M. Furst is an Associate Professor of Chemical
Engineering at the University of Delaware and Director of the Center
for Molecular and Engineering Thermodynamics. His research focuses
on the physics and chemistry of colloidal, polymeric, biomolecular,
and other "soft" materials, with engineering applications in
materials for energy conversion, structured and complex fluid
stability and rheology, nanotechnology and biotechnology.
Professor
Patrick S. Doyle is an Associate Professor in the Department of
Chemical Engineering at the Massachusetts Institute of Technology.
His research focuses on understanding the rheology and dynamics of
single polymers, biomolecules, and magnetic colloids under forces
and fields. His group has expertise in visualizing single DNA
molecules in nano/microfluidic devices, synthesizing functional
microparticles and modeling complex fluids using mesoscale
simulation techniques.
Patrick T. Spicer is a Technical Section Head in the Procter and
Gamble Company’s Complex Fluids Group in Corporate Engineering. His
team focuses on fundamental study of microstructured liquids as well
as process and product development using complex fluids. His
research interests include surfactant phase equilibria and rheology,
complex fluid microstructural dynamics, and colloid and nanoparticle
production.
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Colloidal Dispersion
Rheology /
Microrheology: Theory, Practice and Applications
Instructors: Prof. Jan Mewis and Prof. Norman Wagner
Goal
The course is designed to be an introduction to the rheology of
colloidal dispersions with emphasis on practical measurement and
interpretation of rheological measurements on colloidal dispersions.
The object is to provide the participants with:
- a qualitative understanding of the various phenomena that
contribute to the rheology of suspensions;
- scaling relations and quantitative laws to predict the basic
rheology of such systems;
- strategies to measure, characterize and design suspensions
with well defined processing or application properties.
Who Should Take This Course
It is appropriate for students and practitioners of colloid
rheology in industry as well as academia. A basic understanding of
physical chemistry is necessary with some familiarity with colloidal
science and basic rheology helpful but not required.
Duration
Two full days with time for discussions of relevant and practical
problems (see below).
Course Concept
The suspension course is structured so as to build upon the
fundamental understanding of how various properties of colloids and
their interactions lead to the observed rheological behavior in a
systematic treatment. This starts with systems where only purely
hydrodynamic effects are present (i.e., suspensions with
non-colloidal particles). Next, colloidal particles are introduced;
with Brownian motion but without any particle interaction force.
After that, systems with additionally repulsive interparticle forces
are dealt with: i.e., colloidally stable systems. Finally attractive
forces are added which can lead to flocculated suspensions and
colloidal gels. The methods of rheological measurement design and
execution are discussed, treating the special difficulties that
arise in the case of suspensions. Case studies will be analyzed to
illustrate the basic concepts of the course. Finally, special
advanced topics are to be included depending on the interest of the
students. Time will be available for a question and answer session
based on problems and issued submitted by students prior to the
course.
Course Outline
1. Rheological Concepts and Rheological
Phenomena in Colloidal Dispersions (2 hrs) |
|
- Basis rheological concepts
- Overview of rheological phenomena in suspensions
(based on case studies)
- Introduction to Colloid Science
|
2. Hydrodynamic Effects (Suspensions of
Large Particles) (1 hrs) |
|
- Dilute systems: Relative viscosity and Einstein
relation
- Semi-dilute systems: Hydrodynamic interactions
- Concentrated systems: Maximum packing,
viscosity-concentration relations, effect of particle
size distribution
|
3. Suspensions of Brownian Particles (1.5
hrs) |
|
- Mechanism of Brownian motion
- Contribution of Brownian motion to the viscosity
- Viscoelasticity in suspensions of Brownian Hard
Spheres (scaling relations)
- Structure- Property Relations: Shear thinning and
shear thickening
|
4. Colloidally Stable Suspensions (2 hrs) |
|
- Electrostatic and Steric stabilization, resulting
suspension structure
- Effect of interparticle repulsion on dilute
suspensions
- Viscosity of concentrated stable suspensions,
scaling relations
- Viscoelastic effects, link to interparticle
potential, scaling relations
|
5. Flocculated Suspensions (2 hrs) |
|
- Mechanisms of flocculation (electrostatic,
depletion, bridging…)
- Structure of flocculated systems (flocs,
agglomerates, particle gels; their description in RDF,
fractals, percolation theory, stat diagrams)
- Viscosity of dilute, flocculated systems
- Gels and glasses
- Thixotropy (reversible time effects)
|
6. Rheological Measurements of
Suspensions (1.5 hrs) |
|
- Special requirements and problems (based on case
studies)
- Measurement strategies
|
7. Formulation of suspensions for
controlled rheology (1.5 hrs) |
|
- Design rules for formulation suspensions with a
given rheology (based on case studies)
|
8. Advanced Topics in Colloidal
Suspension Rheology (depending on student preferences) (2-3
hrs) |
|
- Suspensions in viscoelastic media (filled polymers,
nanocomposites)
- Suspensions containing non-spherical particles
(fibers, rods,..)
- Microrheology
- Etc…
|
Instructors: Prof. Eric M. Furst, Prof. Patrick S. Doyle, and
Patrick T. Spicer
For decades, conventional (macroscopic) rheology has been
employed as a powerful method to characterize and understand complex
biological, technological and industrial soft materials. The past
decade, in turn, has seen the development of microrheology, in which
the motion of colloidal tracer particles is related to the
viscoelastic properties of the surrounding material. Significantly,
microrheological measurements require mere microliters of sample,
provide an extended range of frequencies, enable spatially resolved
rheological measurements, and other benefits. For these reasons,
microrheology has emerged as a powerful complement to traditional
bulk rheological characterization.
This short course will present a broad overview of microrheology,
emphasizing the underlying theory, practical aspects of its
implementation and current applications in academic and industrial
laboratories. The microrheology literature continues to rapidly
evolve, and applications are expanding at an accelerating pace.
Participants of this course will learn the key methods and
techniques. For instance, microrheological measurements can be as
simple as recording video microscopy data. As long as the analysis
and sources of experimental error are accounted for appropriately,
these simple experiments can yield rich rheological information. The
course will cover topics ranging from active microrheology using
laser or magnetic tweezers to passive microrheology, such as
multiple particle tracking and diffusing wave spectroscopy. Overall,
this course will provide a comprehensive introduction to
microrheology for industrial and academic researchers who either
wish to become informed in this relatively new field of rheology, or
seek to incorporate these methods in their own research.
Course Outline
1. Introduction and overview
|
2. Active microrheology |
|
a. Laser tweezers |
|
|
-
Principles of optical trapping
-
Practical aspects of trapping
-
Back focal plane detection
|
|
b. Magnetic tweezers |
|
|
- Principles
- Practice
|
3. Passive microrheology |
|
a. Introduction to passive microrheology / tracer particle microrheology |
|
|
- Multiple particle tracking
- Laser tracking microrheology
- Light scattering tracer particle microrheology
|
|
b. Generalized Stokes-Einstein
relationship |
|
|
- Langevin equation
- Linear response theory
|
|
c. Experimental methods |
|
|
- Video microscopy
- Particle tracking
- Two-point microrheology
- Back focal plane microrheology
- Light scattering microrheology
- DWS / high frequency microrheology
|
|
d. Analysis |
|
|
- Heterogeneous materials and trajectory statistics
- Temporal heterogeneity
- Spatial heterogeneity
- Non-ergodicity in tracer particle microrheology
- Results from the literature
|
4. Issues and artifacts |
|
- Particle surface chemistry
- Depletion layers
- Chemistry effects
- Errors in particle tracking
|
5. Applications of microrheology |
|
- Industrial applications
- Kinetic processes and compositional variations
- Mixing and sample preparation effects
- Microfluidic microrheology and shear history
- Interfacial microrheology
- Non-linear microrheology
- Microrheology of gelation and biomaterials screening
|
|
|
|
|
Return to Contents
Short course registration includes a complete set of
course notes. Payment can be made on line with MasterCard,
Visa, Discover, or American Express.
Registration Fee for |
Through 9/10/10 |
After 9/10/10 |
Two-Day Course (Colloidal Dispersion
Rheology) |
|
|
|
Member |
$575 |
$675 |
|
Non-Member* (includes
membership for 2011) |
$630 |
$730 |
|
Student Member |
$325 |
$425 |
|
Student Non-Member*
(includes student membership for 2011) |
$350 |
$450 |
One-Day Course (Microrheology) |
|
|
|
Member |
$340 |
$440 |
|
Non-Member* (includes
membership for 2011) |
$395 |
$495 |
|
Student Member |
$190 |
$290 |
|
Student Non-Member*
(includes student membership for 2011) |
$215 |
$315 |
First Day of Colloidal
Dispersion Rheology + Microrheology** |
|
|
|
Member |
$650 |
$750 |
|
Non-Member* (includes
membership for 2011) |
$705 |
$805 |
|
Student Member |
$375 |
$475 |
|
Student Non-Member*
(includes student membership for 2011) |
$400 |
$500 |
|
|
|
|
|
*Non-members who
are registered to attend the 82nd Annual
Meeting may register for the short course at the member rates.
**Includes a complete set of notes for
both courses. |
Cancellations for the short course received by
electronic mail (c/o The Local Arrangements Chair, Andy Kraynik,
amkrayn@sandia.gov) by
September 10, 2010
will be refunded minus a $50 administrative charge. No refunds
will be granted after that date. Each class is limited to 40 students.
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Questions can be directed to Professor Michael J.
Solomon, University of Michigan, current chair of the SOR
Education Committee, at
mjsolo@umich.edu. |